Transient CO desorption from thin Pt films induced by mid-IR pumping
نویسندگان
چکیده
Resonant and off-resonant mid-infrared pump–probe spectroscopy is used to measure the vibrational dynamics of CO adsorbed thin (0.2 nm, 2 10 nm) heterogeneous Pt layers in an aqueous solution. The transient signals observed with resonant pumping are dominated by relaxation internal stretch vibration a lifetime T1 ∼ 3 ps all cases. Off-resonant suppresses that contribution signal singles out signal, which attributed heating metal layer as well desorption molecules. Due small photon energy eV) pump pulses, mechanism must be thermal, case yield depends exclusively on fluence absorbed light not its wavelength. facilitate desorption, despite relatively low pulse fluence, they concentrate volume.
منابع مشابه
Kinetic study of CO desorption from cathodic electrochemically treated carbon paper supported Pt electrodes
Platinum particles were grown directly by an electrodeposition process on electrochemically treated carbon paper (CP) for kinetic study of carbon monoxide (CO) desorption. The treatment on CP was performed by applying −2 V for cathodic oxidation over 5 min. Treated CP was characterized by FTIR to investigate the oxygen groups on its surface. CO surface coverage at each temperature was determine...
متن کاملCollision-induced desorption in 193-nm photoinduced reactions in (O2+CO) adlayers on Pt(112).
The spatial distribution of desorbing O(2) and CO(2) was examined in 193-nm photoinduced reactions in O(2)+CO adlayers on stepped Pt (112)=[(s)3(111)x(001)]. The O(2) desorption collimated in inclined ways in the plane along the surface trough, confirming the hot-atom collision mechanism. In the presence of CO(a), the product CO(2) desorption also collimated in an inclined way, whereas the incl...
متن کاملVacuum Pumping Study of Titanium-zirconium-vanadium Thin Films*
VACUUM PUMPING STUDY OF TITANIUM-ZIRCONIUM-VANADIUM THIN FILMS* Yulin Li and Simon Ho, LEPP, Cornell University, Ithaca, NY 14853, USA Abstract Vacuum pumping via non-evaporable getter (NEG) thin film deposited directly onto the interior of a vacuum chamber is a novel way to achieve extreme high vacuum. As part of R&D efforts for the proposed Energy Recovery Linac at Cornell, the pumping perfor...
متن کاملMid-IR plasmonics and photomodification with Ag films
The optical properties of semicontinuous silver films have been studied in the mid infrared. The film extinction spectra are shown to be well tailored by the deposition conditions and post-fabrication photomodification with both nanosecond and picosecond laser pulses at 10.6 μm. The photomodification results in a decrease of the extinction above the laser wavelength. We find that the induced ch...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of Chemical Physics
سال: 2021
ISSN: ['1520-9032', '1089-7690', '0021-9606']
DOI: https://doi.org/10.1063/5.0041216