Transient CO desorption from thin Pt films induced by mid-IR pumping

نویسندگان

چکیده

Resonant and off-resonant mid-infrared pump–probe spectroscopy is used to measure the vibrational dynamics of CO adsorbed thin (0.2 nm, 2 10 nm) heterogeneous Pt layers in an aqueous solution. The transient signals observed with resonant pumping are dominated by relaxation internal stretch vibration a lifetime T1 ∼ 3 ps all cases. Off-resonant suppresses that contribution signal singles out signal, which attributed heating metal layer as well desorption molecules. Due small photon energy eV) pump pulses, mechanism must be thermal, case yield depends exclusively on fluence absorbed light not its wavelength. facilitate desorption, despite relatively low pulse fluence, they concentrate volume.

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ژورنال

عنوان ژورنال: Journal of Chemical Physics

سال: 2021

ISSN: ['1520-9032', '1089-7690', '0021-9606']

DOI: https://doi.org/10.1063/5.0041216